At last and After all

At last adverb - As the end result of a succession or process.

After all and at last are semantically related in in the end topic. In some cases you can use "After all" instead an adverb phrase "At last", when it comes to topics like finally, eventually, in the course of time.

After all adverb - In spite of expectations.

At last and after all are semantically related in in the end topic. You can use "At last" instead an adverb phrase "After all", if it concerns topics such as finally, eventually, in the course of time.